Prerequisites :
Site should be created using developer template.
#CODE STARTS HERE
$programFiles = [environment]::getfolderpath("programfiles")
add-type -Path $programFiles'\SharePoint Online Management Shell\Microsoft.Online.SharePoint.PowerShell\Microsoft.SharePoint.Client.dll'
Write-Host 'Ready to enable Sideloading'
$siteurl = Read-Host 'Site Url'
$username = Read-Host "User Name"
$password = Read-Host -AsSecureString 'Password'
$outfilepath = $siteurl -replace ':', '_' -replace '/', '_'
try
{
[Microsoft.SharePoint.Client.ClientContext]$cc = New-Object Microsoft.SharePoint.Client.ClientContext($siteurl)
[Microsoft.SharePoint.Client.SharePointOnlineCredentials]$spocreds = New-Object Microsoft.SharePoint.Client.SharePointOnlineCredentials($username, $password)
$cc.Credentials = $spocreds
$site = $cc.Site;
$sideLoadingGuid = new-object System.Guid "AE3A1339-61F5-4f8f-81A7-ABD2DA956A7D"
$site.Features.Add($sideLoadingGuid, $true, [Microsoft.SharePoint.Client.FeatureDefinitionScope]::None);
$cc.ExecuteQuery();
Write-Host -ForegroundColor Green 'SideLoading feature enabled on site' $siteurl
#Activate the Developer Site feature
}
catch
{
Write-Host -ForegroundColor Red 'Error encountered when trying to enable SideLoading feature' $siteurl, ':' $Error[0].ToString();
}
#CODE ENDS HERE
In your SPO Management Shell enter the url of the site you want to deploy the solution, the administrator username and the password. The powershell will take care of the rest.